You will need:
- A selection of small geodes.
- Some 2 Molar hydrochloric acid.
- A beaker.
- A hammer and a mat or other surface to hammer on.
- Eye and hand protection.
What you do
Experiment 1
- Take a geode and place it in the beaker, then put on your eye and hand protection.
- Drop some of the hydrochloric acid on the geode and watch if it starts to bubble and froth.
Experiment 2
- Take a fresh geode and place it on a mat.
- While wearing your hand and eye protection, hit the geode with the hammer. Hit firmly to get it to crack but try not to smash it entirely. You may find it useful to stick the geode to the mat with Blu Tack, or hold it with tongs (not your fingers).
- Once cracked, have a look at what you find inside.
What's going on?
Geodes form in both sedimentary rocks and in igneous rocks (rocks formed from cooled lava). Although these are very different ways for rocks to form, they both can produce rocks with holes in them, either from escaping gas or from water washing minerals away. Although this seems to be a plausible explanation for their formation it may not be the entire story. It is still unclear why this should lead to the spherical shells of rock which are easily removed from the bulk of the rock around them.
If the rock is porous, water can flow into the cavity, carrying dissolved minerals. These minerals are deposited on the inside of the cavity in the same way that limescale would build up on a sink.
Over a long period of time, over 200 million years, the minerals form crystals which can fill the entire cavity. If the minerals are deposited slowly, large crystals form on the inside. If the minerals are deposited more quickly - by water flowing more rapidly through the cavity - the crystals are small and there tends to be layers of different coloured deposits.
The colour of the crystals inside the cavity is determined by the mineral content of the water that flowed through it. Most often the water contains silicon dioxide which produces white quartz crystals, but other minerals can give the quartz colour, or produce entirely different crystals.
When concentrated hydrochloric acid is dropped onto the geode, if it is a sedimentary geode made of limestone, the limestone will react. Limestone is calcium carbonate and the reaction with hydrochloric acid produces calcium chloride, water and carbon dioxide. It is the carbon dioxide which produces the fizzing and bubbling.
Special safety advice
Eye and hand protection should be worn, along with long sleeves when cracking open the geodes. Don't be tempted to hold the geode with your fingers. Anyone observing should be far enough away to not be hit by splinters of rock. Wear appropriate protection with the hydrochloric acid and do not try to break open this geode and there may be residual acid on it.
This film clip can be viewed on Planet SciCast.
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