Remember last week when Jim Garrett asked
“A colleague has been attempting to demonstrate the displacement of tin (as "beautiful crystals") onto a 'zinc tree' placed into tin(II) chloride solution. However all that was obtained was a 'furry grey solid'. This has raised a lot of questions & investigation, but no definitive answer. Included in the discussion was, for example, why copper placed into silver nitrate solution first goes black/grey before the (expected) silver crystals develop. Any suggestions/explanations would help solve a lot of friendly argument!”
Roy Lowry was quick to point out that this is not just a chemical effect; physics gets a look in too!
“Firstly, the physics: anything that looks “silvery” is reflecting light due to a very smooth surface, much like a mirror. A very rough surface scatters the light that falls on it in all directions; hence it appears black as only a very small proportion of the light from the surface makes it to the eye. Something in between will look grey.
Now the chemistry: when a material crystallises out, the size of the crystals depends on how quickly they are formed. If the concentration of tin in solution is low, only a few crystals will form, but they will have relatively large, smooth surfaces and reflect the light they will look silvery. However, if the concentration is high, lots of very small crystals will form, scattering the light and looking black or grey.
The same thing happens on the copper. Initially lots of small crystals of silver start to form all over the surface turning it black. However, as they grow some outgrow others and become large enough to become mirror-like and silvery (not bad for silver!)”
Tim Bloomfield agrees
“The size of the crystals is down to the speed at which they grow. The faster they grow, the smaller and more numerous they will be. To get larger crystals, use a more dilute solution. As the metal ions/atoms approach the surface to find their niche, if they are “lonely”, they will find the most attractive spot in the correct alignment in a pre-existing crystal. If there is a concentrated solution, then an atom which settles in a less than perfect position will be rapidly buttressed there by freshly-arriving comrades, and another tiny crystal has started. In a dilute solution the atom in a less than ideal location has a lower “activation energy” in relation to re-dissolving, and is more likely to do so than a well positioned one.
As the silver nitrate solution becomes more dilute, larger crystals will be formed. It would seem that either a few “perfect” crystals grow at the expense of the others, or simply grow over them. All microscopic crystals are black because their many tiny facets absorb rather than reflect light. Powdered platinum (used as a catalyst) in know as “Platinum black” because it is.”
Thanks for that scientists on this occasion the scientist was NOT stumped!
This week’s stumper comes from Anne Duncan who asks
“Can ordinary flour that has been mixed with water to form a gloopy substance or held in suspension until it settles be reversed by evaporation, or does the flour irreversibly change once mixed with water?
No heating is involved so it would seem to be reversible but the gloopy, doughy product seems irreversible. No-one I have spoken to seems to know the answer and yet in primary school mixing flour with water is a common activity to do with solubility! Is there someone there who can solve my problem?”
We hope so Anne.
If you can help or have a burning question of your own then send us
an email with STUMP THE SCIENTIST in the subject line to
planet-science.news@nesta.org.uk